Oxomolybdenum(V) Complexes of Some Multidentate N-O Donors
| Main Authors: | S. N. PODDAR, G. C. SAMANTA, G. MUKHERJEE, S. GHOSH |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1985
|
| Subjects: | |
| Online Access: |
https://zenodo.org/record/6298816 |
Daftar Isi:
- Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta-700 032 Manuscript received 25 November 1983, revised 13 June 1984, accepted 8 November 1984 A number of oxomolybdenum(V) complexes of some multidentate N-O donors in the form of Schiff bases have been synthesised and studied. The Schiff bases were obtained by condensing aromatic acid hydrazides with salicylaldehyde (ligands designated as L1H2) and with biacetylmonoxime (ligands designated as L2H2). All these ligands exhibit tridentate function in forming the complexes. The ligands L1H2 formed complexes of the type MoO(L1H)Cl2 (Type A), whereas L2H2 yielded complexes of the type Mo2O3 (L2H)2Cl2 (Type B). All the type A complexes are mononuclear, while the type B complexes are binuclear with oxygen-bridging between two Mo atoms. The isolated complexes were characterised by elemental analysis, spectroscopic (uv-visible, ir), magnetic and conductance data.