Thermodynamic Study of Complexation of Some Transition Metal Ions with 2-Substituted Thiazolidine-4-Carboxylic Acids in Aqueous Medium**
| Main Authors: | P. RAMESH, B. VINOD KUMAR, M. G. RAM REDDY |
|---|---|
| Format: | Article Journal |
| Bahasa: | eng |
| Terbitan: |
, 1983
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| Subjects: | |
| Online Access: |
https://zenodo.org/record/6348401 |
Daftar Isi:
- Department:of Chemistry, Osmania University, Hyderabad-500 007 Manuscript received 12 July 1982, accepted 10 December 1982 Potentiometric titration technique has been applied to study the complex equilibria of 2-propyl thiazolidine-4-carboxylic acid, 2-phenyl thiazolidine-4-carboxylic acid and 2(2')-fury) thiazolidine-4-carboxylic acid with Mn(II), Co(ll), Ni(II), Cu(II) and Zn(II) at different ionic strengths and temperatures. Thermodynamic functions ( ∆G#, ∆H#, ∆S#), electrostatic and cratic components have been determined. The effect of dielectric constant on stabilities is discussed.