Synthesis of Hexa(p-tert-butyl)hexa(carboxylic acid)calix[6]arene from Hexa(p-tert-butyl)hexa(ethyl ester)calix[6]arene
| Main Author: | Firdaus |
|---|---|
| Format: | Article |
| Terbitan: |
International Journal of ChemTech Research
, 2017
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| Subjects: | |
| Online Access: |
http://repository.unhas.ac.id/handle/123456789/24029 |
Daftar Isi:
- The aim of this research is to finf out of synthesis method of calix[6]arene derivative for sensor of ESI
- Abstract : Hexa(p-tert-butyl)hexa(carboxylicacid)calix[6]arene was synthesized from hexa (p-tert-butyl)hexa(ethylester)calix[6]arene as a raw material. The target compound obtained by hydrolyzing hexa(p-tert-butyl)hexa(ethylester)calix[6]arene in aqueous KOH-ethanol 96%. Synthesis products were identified and characterized by melting point, thin layer chromatography (TLC), FTIR, 1H-NMR and 13C-NMR spectrometer. Compound of hexa(ptert-butyl)hexa(carboxylicacid)calix[6]arene was obtained as a white solid (62.38% recovery), a melting point of 326-328??C, and TLC (SiO2, ethanol : ethyl acetate = 1 : 1 v/v, R = 0.93).