Simple and Green Adipic Acid Synthesis from Cyclohexanone and/or Cyclohexanol Oxidation with Efficient (NH4)xHyMzPMo12O40 (M: Fe, Co, Ni) Catalysts
| Main Authors: | Mouanni, Sihem, Mazari, Tassadit, Benadji, Sihem, Dermeche, Leila, Marchal-Roch, Catherine, Rabia, Cherifa |
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| Format: | Article info application/pdf Journal |
| Bahasa: | eng |
| Terbitan: |
Department of Chemical Engineering - Diponegoro University
, 2018
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| Subjects: | |
| Online Access: |
https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1749 https://ejournal2.undip.ac.id/index.php/bcrec/article/view/1749/1617 https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/1749/363 https://ejournal2.undip.ac.id/index.php/bcrec/article/downloadSuppFile/1749/364 |
Daftar Isi:
- The oxidation of cyclohexanone and/or cyclohexanol to adipic acid (AA) was performed at 90 °C with a reaction time of 20 h, in the presence of H2O2 as oxidant and transition metal substituted ammonia polyoxometalates of formula, (NH4)xHyMzPMo12O40 (M: Fe, Co, or Ni, and x = 2.5 or 2.28) as catalysts. The catalytic results showed that the AA yield is sensitive to the transition metal nature and to the reaction conditions (sample weight and substrate amount). The (NH4)2.29H0.39Co0.16PMo12O40 was found to be the better catalytic system toward AA synthesis from cyclohexanone oxidation, with 40% of AA yield Copyright © 2018 BCREC Group. All rights reservedReceived: 12nd November 2017; Revised: 18th February 2018; Accepted: 19th February 2018; Available online: 11st June 2018; Published regularly: 1st August 2018How to Cite: Mouanni, S., Mazari, T., Benadji, S., Dermeche, L., Marchal-Roch, C., Rabia, C. (2018). Simple and Green Adipic Acid Synthesis from Cyclohexanone and/or Cyclohexanol Oxidation with Efficient (NH4)xHyMzPMo12O40 (M: Fe, Co, Ni) Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (2): 386-392 (doi:10.9767/bcrec.13.2.1749.386-392)